LOL yes — he was with Cap on the Lemurian Star, summoned him in the hospital, attacked him in the elevator, arrested him after Bucky kicked his ass, and fought Sam in the Triskelion.
Fellow got around, really.
He’s also the one that walked into the Triskelion launch room and did the fight to early launch the Helicarriers, which was the fight/showdown with Agent 13